Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 59, Issue 5, Pages 2095-2099Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201912564
Keywords
alkylboronates; borylation; organocatalysis; photochemistry; radical reactions
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Funding
- National Natural Science Foundation of China [21772110, 21822304]
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Utilizing pyridine catalysis, we developed a visible-light-induced transition-metal-free radical borylation reaction of unactivated alkyl bromides that features a broad substrate scope and mild reaction conditions. Mechanistic studies revealed a novel nucleophilic substitution/photoinduced radical formation pathway, which could be utilized to trigger a variety of radical processes.
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