Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 59, Issue 4, Pages 1516-1520Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201912315
Keywords
allyl ligands; gold(III) complexes; pi complexes; structural elucidation
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Funding
- Research Council of Norway [185513/I30, 221801/F20]
- FRINATEK Grant [250044]
- Center of Excellence Grant [262695]
- Research Council of Norway through the Norwegian NMR Platform, NNP [226244/F50]
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A highly asymmetric Au-III eta(3)-allyl complex has been generated by treating Au(eta(1)-allyl)Br(tpy) (tpy=2-(p-tolyl)pyridine) with AgNTf2. The resulting eta(3)-allyl complex has been characterized by NMR spectroscopy and X-ray crystallography. DFT calculations and variable temperature H-1 NMR suggest that the allyl ligand is highly fluxional.
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