Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 59, Issue 16, Pages 6520-6524Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201912753
Keywords
arenes; cross-coupling; electrochemistry; nickel; reaction mechanisms
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Funding
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- NSF of China [21821002, 21772222]
- S&TCSM of Shanghai [17JC1401200, 18JC1415600]
- China Postdoctoral Science Foundation [2019M661675]
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A highly regioselective Ni-catalyzed electrochemical reductive relay cross-coupling between an aryl halide and an alkyl halide has been developed in an undivided cell. Various functional groups are tolerated under these mild reaction conditions, which provides an alternative approach for the synthesis of 1,1-diarylalkanes.
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