Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 59, Issue 26, Pages 10242-10251Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201911898
Keywords
asymmetric reactions; catalysis; C-H bond functionalization; chiral NHC; transition metals
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Funding
- Ministere de lEnseignement Superieure, de la Recherche et de lInnovation (MESRI)
- Agence Nationale de la Recherche [ANR-15-CE07-0012-01]
- Agence Nationale de la Recherche (ANR) [ANR-15-CE07-0012] Funding Source: Agence Nationale de la Recherche (ANR)
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The asymmetric functionalization of C-H bond is a particularly valuable approach for the production of enantioenriched chiral organic compounds. Chiral N-heterocyclic carbene (NHC) ligands have become ubiquitous in enantioselective transition-metal catalysis. Conversely, the use of chiral NHC ligands in metal-catalyzed asymmetric C-H bond functionalization is still at an early stage. This minireview highlights all the developments and the new advances in this rapidly evolving research area.
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