Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 59, Issue 49, Pages 21840-21856Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201916473
Keywords
functional materials; interfacial polymerization; nanoscale monomers; simultaneous polymerization; superspreading
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Funding
- National Natural Science Foundation of China [21425314]
- National Program for Special Support of Eminent Professionals
- Youth Innovation Promotion Association CAS [2019028]
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Interfacial polymerization, where a chemical reaction is confined at the liquid-liquid or liquid-air interface, exhibits a strong advantage for the controllable fabrication of films, capsules, and fibers for use as separation membranes and electrode materials. Recent developments in technology and polymer chemistry have brought new vigor to interfacial polymerization. Here, we consider the history of interfacial polymerization in terms of the polymerization types: interfacial polycondensation, interfacial polyaddition, interfacial oxidative polymerization, interfacial polycoordination, interfacial supramolecular polymerization, and some others. The accordingly emerging functional materials are highlighted, as well as the challenges and opportunities brought by new technologies for interfacial polymerization. Interfacial polymerization will no doubt keep on developing and producing a series of fascinating functional materials.
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