Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 362, Issue 2, Pages 337-343Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201901253
Keywords
alcohols; bond-weakening; C-H activation; photoredox catalysis; regioselectivity; silicates
Categories
Funding
- JSPS [JP19J23157]
- JSPS KAKENHI [JP16H04239, JP18K06545, JP17H06442]
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The development of catalyst-controlled site-selective C(sp(3))-H functionalization is a current major challenge in organic synthesis. This paper describes DFT-guided identification of pentavalent silicate species as a novel bond-weakening catalyst for the alpha-C-H bonds of alcohols together with a photoredox catalyst and a hydrogen atom transfer catalyst. Specifically, Martin's spirosilane accelerated alpha-C-H alkylation of alcohols.
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