Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 30, Issue 12, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201910048
Keywords
exfoliation; freezing-and-thawing approach; high yield; micro-supercapacitors; MXenes
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Funding
- National Science Foundation of China [51733003, 21674025]
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MXene, as a new member of the two-dimensional (2D) material family, has been widely studied. However, people often pay close attention to the versatility of MXene while ignoring its low exfoliation yield. In this work, a simplified and effective strategy to exfoliate multilayer-MXene via the gentle water freezing-and-thawing (FAT) approach is proposed. The volume expansion of intercalated water can promote the exfoliation of MXene nanosheets. The yield of large FAT-MXene flakes with special wrinkles can reach 39% after four cycles of the FAT process. Moreover, combining with sonication treatment can boost the yield of small MXene to a record high value of 81.4%. With the help of a commercial interdigital mask, an on-chip all-MXene micro-supercapacitor (MSC) assembled by large FAT-MXene is fabricated, exhibiting high areal and volumetric capacitance of 23.6 mF cm(-2) and 591 F cm(-3), respectively. This remarkable electrochemical performance of MXene-MSC also confirms the high quality of MXene through this FAT strategy. This study may open up a new method to simultaneously boost the yield of MXene with small or large flake sizes, facilitating large-scale and size-dependent research on MXene.
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