4.8 Article

Boron-Doped Nanocrystalline Diamond-Carbon Nanospike Hybrid Electron Emission Source

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 11, Issue 51, Pages 48612-48623

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.9b17942

Keywords

nanocrystalline diamond; carbon nanospike; one-step growth; field electron emission; microplasma illumination

Funding

  1. Flemish Methusalem NANO network
  2. Polish National Science Center (NCN) [2016/21/B/ST7/01430, 2015/17/D/ST5/02571]
  3. National Center for Science and Development Grant Techmatstrateg [347324]
  4. Foundation for Polish Science [POIR.04.04.00-00-1644/18]
  5. Institute for Basic Science [IBS-R004]
  6. Faculty of Electronics, Telecommunications and Informatics of the Gdansk University of Technology

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Electron emission signifies an important mechanism facilitating the enlargement of devices that have modernized large parts of science and technology. Today, the search for innovative electron emission devices for imaging, sensing, electronics, and high-energy physics continues. Integrating two materials with dissimilar electronic properties into a hybrid material is an extremely sought-after synergistic approach, envisioning a superior field electron emission (FEE) material. An innovation is described regarding the fabrication of a nanostructured carbon hybrid, resulting from the one-step growth of boron-doped nanocrystalline diamond (BNCD) and carbon nanospikes (CNSs) by a microwave plasma-enhanced chemical vapor deposition technique. Spectroscopic and microscopic tools are used to investigate the morphological, bonding, and microstructural characteristics related to the growth mechanism of these hybrids. Utilizing the benefits of both the sharp edges of the CNSs and the high stability of BNCD, promising FEE performance with a lower turn-on field of 1.3 V/mu m, a higher field enhancement factor of 6780, and a stable FEE current stability lasting for 780 min is obtained. The microplasma devices utilizing these hybrids as a cathode illustrate a superior plasma illumination behavior. Such hybrid carbon nanostructures, with superb electron emission characteristics, can encourage the enlargement of several electron emission device technologies.

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