Journal
MOLECULAR CATALYSIS
Volume 482, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.mcat.2019.110666
Keywords
Cooperative vinylogous anomeric based oxidation; Acid catalysis; Nanostructured catalyst; (3 '-indolyl)pyrazolo[3,4-b]pyridines; Multicomponent reaction
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Funding
- Bu-Ali Sina University
- Iran National Science Foundation (INSF) [98001912]
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A novel nanostructured melamine-based organo solid acid with phosphorus acid tags was designed, synthesized and fully characterized. The catalytic activity of the resulted melamine hexakis(methylene)hexakis(phosphonic acid) (MHMHPA) as a heterogeneous catalyst was also investigated via an one-pot reaction between cyanoacetylindole, 3-methyl-1-phenyl-1H-pyrazol-5-amine, and an aromatic aldehyde. (3'-Indolyl)pyrazolo[3,4-b] pyridines were produced in good yields under refluxing ethanol. The solid catalyst can be recovered easily and reused without a significant loss of its catalytic activity.
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