Journal
INORGANIC AND NANO-METAL CHEMISTRY
Volume 50, Issue 1, Pages 1-7Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/24701556.2019.1661447
Keywords
Ag(Ι )-based MOF; 9; 10-anthraquinone-1; 5-dicarboxylic acid; crystal structure; selective fluorescence sensing; photocatalytic property
Funding
- National Natural Science Foundation of China [21403006]
- Natural Science Foundation of Henan province [182300410212]
- project of Science and Technology Department of Henan Province [182102310636]
- plan of Science and Technology Innovation Team of Henan University [18IRTSTHN006]
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Solvothermal reactions of AgNO3 with 9,10-anthraquinone-1,5-dicarboxylic acid (H2L) and 4,4'-bipyridine (bipy) gave rise to a metal-organic framework, namely [Ag(L)(bipy)](n) (1), which was structurally characterized by elemental analyses, IR spectra, and X-ray diffraction analysis. Single-crystal X-ray diffraction analyses indicate that 1 exhibits a 2D 4(4) topology framework assembled by dinuclear [Ag-2(COO)(2)] units, L and bipy ligands. 1 displays highly sensitivity in the detection of nitrobenzene (NB) as a fluorescent sensor. Moreover, 1 exhibits a relatively good photocatalytic activity towards the degradation of rhodamine B (RhB) in aqueous solution under UV irradiation.
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