Journal
CHEMISTRYSELECT
Volume 4, Issue 40, Pages 11785-11789Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201902532
Keywords
addition reaction; gold catalysis; heterocycle; tetrazole; vinylation
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Funding
- NSFC [21402106]
- Shandong Natural Science Foundation [ZR2018JL013, ZR2018MB014]
- Qufu Normal University for Research Start-up Foundation [bsqd20130115]
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A gold-catalyzed reaction of 2H-tetrazoles with alkynes was described for the efficient synthesis of a variety of N-alkenylated tetrazole derivatives, including N-1 and N-2 vinyl functionalized products which are readily isolated by column chromatography. The reaction mechanism was proposed to be a nucleophilic addition process to the alkyne motif activated by gold catalyst. The reaction features mild reaction condition, simple operation and high yields.
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