Journal
SCIENCE CHINA-MATERIALS
Volume 62, Issue 12, Pages 1846-1856Publisher
SCIENCE PRESS
DOI: 10.1007/s40843-019-1186-4
Keywords
perovskite solar cell (PSC); mixed cations; partial-nucleation; single phase; defects; stability
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Funding
- National Key Research and Development Program of China [2016YFA0202401]
- 111 Project [B16016]
- National Natural Science Foundation of China [51702096, U1705256]
- Fundamental Research Funds for the Central Universities [2018ZD07]
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To date, extensive research has been carried out, with considerable success, on the development of high-performance perovskite solar cells (PSCs). Owing to its wide absorption range and remarkable thermal stability, the mixed-cation perovskite FA(x)MA(1-x)PbI(3) (formamidinium/methylammonium lead iodide) promises high performance. However, the ratio of the mixed cations in the perovskite film has proved difficult to control with precursor solution. In addition, the FA(x)MA(1-x)PbI(3) films contain a high percentage of MA(+) and suffer from serious phase separation and high trap states, resulting in inferior photovoltaic performance. In this study, to suppress phase separation, a post-processing method was developed to partially nucleate before annealing, by treating the as-prepared intermediate phase FAI-PbI2-DMSO (DMSO: dimethylsulfoxide) with mixed FAI/MAI solution. It was found that in the final perovskite, FA(0.92)MA(0.08)PbI(3), defects were substantially reduced because the analogous molecular structure initiated ion exchange in the post-processed thin perovskite films, which advanced partial nucleation. As a result, the increased light harvesting and reduced trap states contributed to the enhancement of open-circuit voltage and short-circuit current. The PSCs produced by the post-processing method presented reliable reproducibility, with a maximum power conversion efficiency of 20.80% and a degradation of similar to 30% for 80 days in standard atmospheric conditions.
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