Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 8, Issue 12, Pages 2205-2208Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201900664
Keywords
nitration; N-alkyl-N-nitrosoanilines; N-alkylnitroanilines; radical reactions
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Funding
- National Natural Science Foundation of China (NNSFC) [21562038]
- Jiangsu Provincial Natural Science Foundation [BK20161328]
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In the presence of dioxygen, an efficient synthesis of nitrated N-alkyl anilines was realized using N-nitroso anilines as the starting material. According to the mechanistic study, the N-nitroso anilines served as a self-providing nitro group source to promote the direct nitration of N-alkylanilines, avoiding the undesired protection of amine group.
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