Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 8, Issue 11, Pages 2042-2045Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201900570
Keywords
Radical Cyclization Reaction; Phosphorylation; Silver-catalyzed; Benzimidazo[2; 1-a]isoquinolin-6(5H)-ones
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Funding
- National Natural Science Foundation of China [21501010, 21971224]
- China Postdoctoral Science Foundation [2019M652561]
- Key Research Projects of Universities in Henan Province [19A350011, 20A150006]
- Henan Province Young Talents Elevation Program [2019HYTP023]
- Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation [2019CL03]
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An efficient and convenient silver-catalyzed procedure was developed for the synthesis of various phosphoryl-substituted benzimidazo[2,1-a]isoquinoline-6(5H)-ones from diarylphosphine oxides and 2-arylbenzoimidazoles. Moreover, the phosphoryl-substituted indolo[2,1-a]isoquinolin-6(5H)-ones could also be achieved by using this strategy under mild reaction conditions in the presence of AgNO3/K2S2O8.
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