Journal
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 7, Issue 22, Pages 18236-18241Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.9b04803
Keywords
Levulinic acid; Cobalt catalyst; gamma-Valerolactone; Homogeneous catalysis; Hydrogenation
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Funding
- Chinese Academy of Sciences [QYZDY-SSW-SLH013]
- Beijing Munic ipal Science & Technology Commission [Z191100007219009]
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A cobalt-based catalytic system composed of Co(BF4)(2).6H(2)O and ligand P(CH2CH2PPh2)(3) was developed for hydrogenation of levulinic acid to y-valerolactone (GVL), which showed high efficiency for this reaction, affording a GVL yield of 95% under atmospheric pressure and 100 degrees C.
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