Journal
ACS CATALYSIS
Volume 9, Issue 12, Pages 11125-11129Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.9b03476
Keywords
manganese; cobalt; oxidation; C-C bond activation; heterocycles
Categories
Funding
- Federal Ministry of Education and Research (BMBF)
- State of Mecklenburg-Vorpommern
- Fonds der Chemischen Industrie [103231]
Ask authors/readers for more resources
Catalytic methods for the site-selective scission of C(sp(3))-C(sp(3)) bonds remain scarcely explored in contrast to the vast literature on C-C coupling. In view of this, we report a means of oxidative C-C single-bond cleavage in morpholines, made possible by a synergy between cobalt and manganese catalysts using air as a benign oxidant. We demonstrate the synthetic utility of this system with the late-stage oxidative cleavage of Linezolid.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available