Journal
NATURE COMMUNICATIONS
Volume 10, Issue -, Pages -Publisher
NATURE PUBLISHING GROUP
DOI: 10.1038/s41467-019-13359-z
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Funding
- National Natural Science Foundation [21421002, 21672242, 21971252]
- Key Research Program of Frontier Sciences (CAS) [QYZDJSSW-SLH049]
- Fujian Institute of Innovation, Chinese Academy of Sciences [FJCXY18040102]
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As a versatile intermediate, difluorocarbene is an electron-deficient transient species, meaning that its oxidation would be challenging. Herein we show that the oxidation of difluorocarbene could occur smoothly to generate carbonyl fluoride. The oxidation process is confirmed by successful trifluoromethoxylation, O-18-trifluoromethoxylation, the observation of AgOCF3 species, and DFT calculations.
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