Journal
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume 646, Issue 13, Pages 625-630Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.201900193
Keywords
Aluminum alkyl compounds; Aluminum; Bis(beta-diketiminate); Dinuclear aluminum complexes; Group 13; Synergy
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Funding
- Fonds der Chemischen Industrie
- Deutsche Forschungsgemeinschaft (DFG) [KR4782/2-1, KR4782/3-1]
- University of Regensburg
- Friedrich Schiller University Jena
- Stiftung Stipendien-Fonds des Verbands der Chemischen Industrie
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A series of ten dinuclear aluminum alkyl complexes based on rigid, semirigid, and flexible bis(beta-diketiminate) ligands (NacNac) has been obtained from the reaction of trimethylaluminum and the corresponding bis(beta-diketimine)s. All compounds were fully characterized using NMR and IR spectroscopy and elemental analysis. The molecular structures of five compounds have been investigated by means of single-crystal X-ray diffraction analysis.
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