Journal
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume 645, Issue 18-19, Pages 1141-1145Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.201900165
Keywords
Halide complex; Antimony; Halogen bonding; Supramolecular interactions; Polyhalogens
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Funding
- Russian Science Foundation [18-73-10040]
- Russian Science Foundation [18-73-10040] Funding Source: Russian Science Foundation
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Reactions of [(SbBr6)-Br-III](3-) with Br-2 in HBr in the presence of N-substituted quinolinium or isoquinolinium cations result in new complexes of hexabromidoantimonates of Sb-V and their polybromide adducts: (N-MeQuin)(2){[SbBr6](Br-3)} (1), (N-MeIsoquin)(2){[SbBr6](Br-3)} (2), and (N-EtQuin)[SbBr6] (3). Thermal stability was studied; estimated energies of supramolecular Br center dot center dot center dot Br interactions were calculated.
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