Journal
WATER RESEARCH
Volume 163, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.watres.2019.114874
Keywords
Short-chain PFAS; GenX; Selective removal; Cationic polymer; Density functional theory
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The emerging classes of perfluorinated alkyl substances (PFAS) (e.g., Perfluorobutanoic add (PFBA), perfluorobutane sulfonic acid (PFBS), GenX, ADONA, and F-53B) are persistent and recalcitrant to removal by conventional treatment techniques. Herein, we report on poly (N-[3-(dimethylamino)propyl] acrylamide, methyl chloride quaternary, DMAPAA-Q) hydrogel matrix as an effective sorbent for sequestering PFAS from different water matrices. The selective removal of 16 PFAS from different classes using DMAPAA-Q polymer was confirmed in surface waters and treated wastewater at environmentally relevant concentration (i.e., <1000 ng/L). The results showed fast removal kinetics with equilibrium time of 60-120 min and a higher removal of sulfonated than carboxylic PFAS, regardless of their chain lengths. These observations were in agreement with adsorption energy calculations of short- and long-chain PFAS on poly DMAPAA-Q hydrogel using density functional theory (DFT). No desorption was observed when the experimental time was extended to 24 h, which gives an added advantage of poly DMAPAA-Q hydrogel over previously reported adsorbents in the literature. In addition, the removal efficiency was not affected under a varying pH range of 4-10. The impact of background anions on PFAS removal by poly DMAPAA-Q hydrogel was tested and found to follow an order of SO42- > Cl- > NO3-. The performance of poly DMAPAA-Qhydrogel was maintained in six consecutive adsorption/regeneration cycles to remove PFAS. The unique fast kinetics and high adsorption activity of poly DMAPAA-Q hydrogel towards PFAS exhibits a great potential for being a promising material for PFAS control. (C) 2019 Elsevier Ltd. All rights reserved.
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