Journal
TRIBOLOGY INTERNATIONAL
Volume 138, Issue -, Pages 204-210Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.triboint.2019.05.039
Keywords
Ester oil; Naphthalene dicarboxylic acid; Lubrication performance; Oxidation stability
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Funding
- National Natural Science Fund [51675006]
- project of Science and Technology Department, Shaanxi Province [2016JZ017]
- open fund of the State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics [LSL-1412]
- local servicing research project of the Education Department of Shaanxi Province [15JF007]
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In this paper, we present the synthesis and tribological properties of two naphthatate-based lubricating oils. The structure and purity of the oils were analyzed using nuclear magnetic resonance spectra and high resolution mass spectra. Their thermal and oxidation stability, flash point and pour point, viscosity and viscosity index, and friction reduction and anti-wear properties were also tested. In the results, the two isooctyl naphthatate-based oils (INA) displayed better lubricating properties than a reference sample of isooctyl sebacate (ISE) on three different friction pairs. The new oils also offered higher oxidation stability than the reference sample. It was found that the stability and lubrication properties of ester-based lubricating oils can be significantly improved by introducing a naphthalene ring into the molecular structure. This is because there is a large a-electron conjugate system on the naphthalene ring, which not only reduces the likelihood of an oxidation chain reaction, but also enables the oil to form an orderly and stable lubricating film on metal surfaces. One of the oils, 2,3-INA, was found have better oxidation stability than the other one, 1,4-INA, because its oxidized groups are positively affected by the steric and conjugation effects of the two ester groups.
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