Journal
TETRAHEDRON LETTERS
Volume 60, Issue 47, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2019.151231
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Funding
- JSPS KAKENHI [JP18H04244, JP17K08209]
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In the long history regarding the development of the transition metal-catalyzed reactions, almost all ligands in metals are classified as the covalent X-type and/or dative L-type ligands. Therefore, exploring the reactivity of the metal complexes bearing the sigma-acceptor, i.e., the Z-ligand, is required. This digest briefly describes our recent results regarding 1) the syntheses of gold complexes featuring the Z-type ligand, and 2) their catalytic reactions, which would be speculated that the electron-withdrawing effect of the Z-ligand on the neighboring gold activated the catalytic reactivity due to the increase in the Lewis acidity. (C) 2019 Elsevier Ltd. All rights reserved.
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