Journal
SYNTHESIS-STUTTGART
Volume 51, Issue 24, Pages 4619-4624Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0039-1690207
Keywords
diboron-mediated; allenes; hydrogenation; semireduction
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Funding
- National Science Foundation [CHE-1414458, CHE-0131124, CHE-0722638]
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A method for the regioselective reduction of the terminal double bond of 1,1-disubstituted allenes has been developed. In the presence of a palladium catalyst, tetrahydroxydiboron and stoichiometric water, allene semireduction proceeds in high yield to afford Z-alkenes selectively.
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