Journal
SYNLETT
Volume 30, Issue 20, Pages 2247-2252Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0039-1690734
Keywords
Friedel-Crafts; cyclization; isochromeno[3,4,b]indolines; deformylative arylation; 3-arylindoles; silver
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Funding
- Japan Society for the Promotion of Science (JSPS) [16K18849]
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We disclose a silver-mediated intramolecular Friedel-Crafts-type cyclization of 2-benzyloxy-3-bromoindolines to afford an untapped family of isochromeno[3,4- b ]indolines and 3-arylindoles, in which deformylative arylation of 2-(4-methoxybenzyloxy)-3-bromoindolines is reported for the first time. The isochromeno[3,4- b ]indolines can be readily transformed into other heterocyclic moieties.
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