Journal
SYNLETT
Volume 31, Issue 19, Pages 1953-1956Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0039-1690743
Keywords
arucadiol; 1-oxomiltirone; [4+2]-benzannulation; gold(III) bromide; copper(II) trifluoromethanesulfonate
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A practical and efficient approach for the total synthesis of arucadiol and 1-oxomiltirone is reported. The key step which involves an intramolecular [4+2] cycloaddition catalyzed by gold(III) bromide or copper(II) triflate leads to the formation of 6-6-6-fused aromatic abietane core.
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