Journal
SYNLETT
Volume 30, Issue 20, Pages 2233-2246Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0039-1690738
Keywords
fluorine; fluorocarbons; main group; reaction mechanisms; C-F bond activation
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Funding
- European Research Council [Fluorofix: 677367]
- EPSRC
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In this Account we describe a series of new reactions that we, and others, have reported that involve the transformation of C-F bonds into C-Mg, C-Al, C-Si, C-Fe and C-Zn bonds. We focus on the use of highly reactive main group nucleophiles and discuss aspects of reaction scope, selectivity and mechanism.
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