Journal
SCIENCE CHINA-CHEMISTRY
Volume 63, Issue 1, Pages 42-46Publisher
SCIENCE PRESS
DOI: 10.1007/s11426-019-9609-9
Keywords
visible-light; organophotocatalysis; oxidative coupling; oxyalkylation
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Funding
- Council of Scientific and Industrial Research (CSIR), and New Delhi [02(0307)/17/EMR-II]
- University Grants Commission (UGC)
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A new visible-light-promoted oxidative coupling of vinylarenes with cyclic ethers has been developed using rose bengal as photocatalyst and tert-butyl hydrogenperoxide (TBHP) as oxidant under ambient air at room temperature. A library of alpha-oxyalkylated ketones with broad functionalities has been synthesized in moderate to good yields. A radical mechanism is suggested for the present protocol
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