Journal
SCIENCE CHINA-CHEMISTRY
Volume 62, Issue 11, Pages 1476-1491Publisher
SCIENCE PRESS
DOI: 10.1007/s11426-019-9629-x
Keywords
radical cascade reaction; functional group migration; unsaturated C-C bonds; C-centered radicals; N-centered radicals
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Funding
- National Natural Science Foundation of China [21831002, 21801039]
- Ten Thousand Talents Program
- Jilin Province Natural Science Foundation [20160519003JH]
- Fundamental Research Funds for the Central Universities [2412018QD007]
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During the past few years, with the rapid development of mild methods for the generation of radical species, great progress in radical cascade reactions of unsaturated C-C bonds has been made. Many radical cascade reactions involve functional groups migration, which leads structurally much more diverse, complex and valuable compounds not easily obtained through other methods. In this review, the recent achievements in unsaturated C-C bonds radical cascade reactions involving migration are summarized.
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