4.8 Review

The sleeping giant: A polymer View on humic matter in synthesis and applications

Journal

PROGRESS IN POLYMER SCIENCE
Volume 100, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.progpolymsci.2019.101182

Keywords

Natural polymer; Humic acid; Ion binding; Redox; Polyamphiphile

Funding

  1. Max Planck Society
  2. National Natural Science Fund for Young Scholars [31600413]
  3. University Nursing Program for Young Scholars with Creative Talents in Heilongjiang Province [UNPYSCT-2017018]
  4. Natural Science Foundation of Heilongjiang Province of China [QC2018019]

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Humic Acid is a natural polymer with high functionality which is omnipresent in Nature, but was up to now hardly considered as an object of polymer synthesis. We review the known structural properties of natural humic acids which are remarkably uniform, independent of source and origin and environment. We then present its simple retrosynthesis in the lab based on a hydrothermal polycondensation process. The for a polymer very unusual properties of Humic Acid, such as pH and redox buffering, strong ion binding, but also its ability to bind and carry both hydrophobic and very hydrophilic molecules make artificial humic acid also an exciting choice as a functional polymer for technical purposes. (C) 2019 Elsevier B.V. All rights reserved.

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