Journal
ORGANOMETALLICS
Volume 38, Issue 22, Pages 4383-4386Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.9b00616
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Funding
- Austrian Science Fund (FWF) [J-4158, P 30221]
- Research Council of Norway [250795]
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A gold(III) complex with the hitherto most electron poor mesoionic carbene ligand is presented. Aqua regia was the oxidizing agent of choice for the synthesis of this unusual organometallic compound. The Au-III complex is redox-rich and also acts as a catalyst for oxazole formation, delivering selectively a completely different isomer in comparison to its Au-I congener.
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