Journal
ORGANOMETALLICS
Volume 38, Issue 21, Pages 4261-4270Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.9b00549
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- American Chemical Society Petroleum Research Fund
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A useful and convenient method for sp(3) C-P(O) bond formation via direct regioselective hydrophosphinylation of simple and readily available alkenes using a lanthanum-based N,N-dimethylbenzylamine complex (La(DMBA)(3)) as a precatalyst is demonstrated. The reaction proceeds with perfect atom economy for a wide range of styrenes with secondary phosphine oxides, giving moderate to excellent yields.
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