Journal
ORGANIC LETTERS
Volume 21, Issue 23, Pages 9483-9486Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b03683
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Funding
- National Key Research and Development Program of China [2018YFC0310903]
- National Natural Science Foundation of China [21572210, 41776136, 81991522]
- NSFC-Shandong Joint Fund for Marine Science Research Centers [U1606403]
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One new dimeric bromopyrrole alkaloid, agelanemoechine, with an unprecedented imidazo [1,5-a] azepin nucleus together with one known dimeric bromopyrrole alkaloid sceptrin were isolated from the marine sponge Agelas nemoechinata. The structure elucidation and absolute configuration assignments were determined by extensive spectroscopic analyses and the comparison of experimental and calculated ECD. Agelanemoechine showed strong pro-angiogenic activity in zebrafish.
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