Journal
ORGANIC LETTERS
Volume 21, Issue 23, Pages 9790-9794Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b04068
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Funding
- National Natural Science Foundation of China [21472128]
- Sichuan Science and Technology Program [2018JY560]
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A rhodium-catalyzed Suzuki-Miyaura coupling reaction via C(O)-C bond activation to form 2-benzoylpyridine N-oxide derivatives is reported. Both the C(O)-C(sp(2)) and C(O)-C(sp(3)) bond could be activated during the reaction with yields up to 92%. The N-oxide moiety could be employed as a traceless directing group, leading to free pyridine ketones.
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