Journal
ORGANIC LETTERS
Volume 21, Issue 22, Pages 9128-9132Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b03514
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The facile synthesis of both saturated and unsaturated tricyclic pyrrolo-pyridones starting from a single readily available, common monocyclic reagent has been developed. An intermolecular annulation via a tandem Buchwald-Hartwig/Heck reaction led to the synthesis of beta-carbolinones. The analogous semisaturated tricyclic pyrrolo-pyridones were prepared in good to excellent yields by sequential Buchwald-Hartwig and Fischer indole reactions. The methods feature mild reaction conditions and good functional group tolerance.
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