Journal
ORGANIC LETTERS
Volume 21, Issue 22, Pages 9109-9113Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b03507
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Funding
- Science and Engineering Research Board (SERB) [CRG/2018/001332]
- Council of Scientific and Industrial Research (CSIR)
- Indian Institute of Science (IISc)
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The addition of a lithium anion of diphenylallylimine to nonracemic sulfinimines was investigated. It was found that the reaction with sulfinimines derived from aliphatic aldehydes afforded the products with excellent diastereoselectivity (>99:1), furnishing the product vicinal diamines in very good yields. Application of the formed product vicinal diamines was demonstrated in the total synthesis of the natural product (-)-epiquinamide.
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