Journal
ORGANIC LETTERS
Volume 21, Issue 20, Pages 8439-8443Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b03201
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Funding
- National Key Research and Development Program of China [2016YFA0602900]
- National Natural Science Foundation of China [21672072, 21472051]
- Guangdong Natural Science Foundation [2018B030308007]
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A straightforward approach for the assembly of different polysubstituted propiolamidnates via palladium catalyzed multicomponent reaction of isocyanides, haloalkynes, and amines has been reported in which the C(sp)-C(sp(2)) and C(sp(2))=N bonds were constructed in one pot. This reaction featured in high efficiency, excellent chemoselectivity, and good functional group compatibility. The synthetic utility of this method was also demonstrated.
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