Journal
ORGANIC LETTERS
Volume 21, Issue 21, Pages 8746-8750Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b03361
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Funding
- ESF research grant NitraMon
- RUDN University Program 5-100
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Herein we describe the design, synthesis, and anion binding properties of bicyclic receptors with two or three anthracenes, which show a turn-on fluorescence response in the presence of nitrate and chaotropic anions in a buffered aqueous solution. The receptor with two anthracenes binds nitrate with 10(3) M-1 affinity and stabilizes it in the inner cavity though electrostatic, hydrogen bonding, and anion-pi interactions.
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