Journal
OPTIK
Volume 208, Issue -, Pages -Publisher
ELSEVIER GMBH
DOI: 10.1016/j.ijleo.2019.163632
Keywords
Co-precipitation; EPR; Gd(3+)ions; NaSrPO4; Photoluminescence
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Funding
- KU Research Professor Program of Konkuk University
- National Research Foundation of Korea (NRF) - Korea government (MSIT) [2018M2B2A9065656]
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Sodium strontium phosphate or NaSrPO4 phosphor activated with gadolinium (Gd3+) was prepared by co-precipitation method. The X-ray diffraction (XRD) pattern confirmed that the phosphor crystallized in a monoclinic phase of NaSrPO4. The Fourier transform infrared spectroscopy (FTIR) data confirmed that the stretching mode frequencies were related to stretching vibrations of (PO4)(3-) group. The photoluminescence emission spectrum showed characteristic emissions of Gd3+ at 313 nm (P-6(7/2)-> S-8(7/2)). The EPR spectrum of gadolinium activated NaSrPO4 phosphor exhibited resonance signals at effective values of g approximate to 5.95, 4.90 and 2.02 indicating the existence gadolinium in trivalent state in the NaSrPO4 phosphor matrix.
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