4.6 Article

Sm3+-activated Y2Mo4O15 red-emitting microparticles with admirable luminescent performance for indoor illumination

Journal

OPTICAL MATERIALS
Volume 97, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.optmat.2019.109382

Keywords

White-LEDs; Red phosphors; Luminescent performance; Rare-earth ions

Funding

  1. National Natural Science Foundation of China [51702172]
  2. Open Fund of the State Key Laboratory of Luminescent Materials and Devices (South China University of Technology) [2018-skllmd-11]
  3. Natural Science Foundation of Ningbo [2018A610042]
  4. Science Research Fund Project of Ningbo University [XYL18015]
  5. K. C. WongMagna Fund in Ningbo University

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Utilizing a facile sol-gel reaction route, we dealt with the fabrication and luminescent properties of Sm3+-activated Y2Mo4O15 red-emitting microparticles. At the excitation of 405 nm, the resultant microparticles showed visible red emission with color purity of 76.7%. According to the detected decay time, the theoretical internal quantum efficiencies of the compounds were analyzed. In addition, temperature-dependent emission spectra were performed to verify the thermal resistance performances of the microparticles. As proof of the suitability of the prepared compounds for solid-state illumination, a white light-emitting diode (WLED) device was packaged using the obtained microparticles, BaMgAl10O17:Eu2+ blue phosphors, (Ba,Sr)(2)SiO4:Eu2+ green phosphors and near-ultraviolet (NUV) chip. The designed WLED lamp enabled emit bright white light with a good chromaticity coordinate of (0.302, 0.394), satisfied color rendering index (78.3) as well as proper correlated color temperature (6552 K).

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