Journal
MOLECULES
Volume 24, Issue 22, Pages -Publisher
MDPI
DOI: 10.3390/molecules24224058
Keywords
organocatalysis; deep eutectic solvents; conjugate addition; maleimides; nitroalkenes
Funding
- Spanish Ministerio de Economia, Industria y Competitividad [CTQ201788171-P, PGC2018-096616-B-I00]
- University of Alicante [VIGROB-173, UADIF18-20, UAUSTI18-05]
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A chiral primary amine-salicylamide is used as an organocatalyst for the enantioselective conjugate addition of alpha,alpha -disubstituted aldehydes to maleimides and nitroalkenes. The reactions are performed in deep eutectic solvents as reaction media at room temperature, leading to the corresponding adducts with enantioselectivities up to 88% (for maleimides) and 80% (for nitroalkenes). Catalyst and solvent can be recovered and reused.
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