Journal
MOLECULES
Volume 24, Issue 23, Pages -Publisher
MDPI
DOI: 10.3390/molecules24234317
Keywords
polypropylene glycol-polyoxytetramethylene glycol block multicopolymers; chain extender; m-phthaloyl chloride; adhesives; structure optimizing
Funding
- National Science Foundation [51903061]
- Natural Science Foundation of Guangdong Province [2018A030313239]
- GDAS Special Project of Science and Technology Development [2018GDASCX-0802, 2017GDASCX-0116]
- Open Project of Guangdong Province Key Laboratory of High Performance and Functional Polymer materials [20170002]
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The high crystallization at room temperature and high cost of polyoxytetramethylene glycol (PTMG) have become obstacles to its application. To overcome these problems, a segment of PTMG can be incorporated into a block copolymer. In this work, polypropylene (PPO) glycol-polyoxytetramethylene (PPO-PTMG) multiblock copolymers were designed and synthesized through a chain extension between hydroxyl (OH)-terminated PPO and PTMG oligomers. The chain extenders, feed ratios of the catalyst/chain extender/OH groups, reaction temperature, and time were optimized several times to obtain a PPO-PTMG with low crystallization and high molecular weight. Multiblock copolymers with low crystallization and high average molecular weight (M-n = 1.0-1.4 x 10(4) Dalton) were harvested using m-phthaloyl chloride as the chain extender. The OH-terminated PPO-PTMG multiblock copolymer with high M-n and a functionality near two was further siliconized by 3-isocyanatopropyltrimethoxysilane to synthesize a novel silyl-terminated polyether. This polyether has an appropriate vulcanizing property and potential applications in sealants/adhesive fields.
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