4.6 Article

Mg-Al layered double hydroxide as an electrolyte membrane for aqueous ammonia fuel cell

Journal

MATERIALS RESEARCH BULLETIN
Volume 119, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2019.110561

Keywords

Layered double hydroxide; Aqueous ammonia fuel cell; Anion exchange membrane fuel cell

Funding

  1. EIG CONCERT-Japan under the Strategic International Collaborative Research Program (SICORP)
  2. Japan Science and Technology Agency (JST) [JPMJSC17C3]

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Mg-Al layered double hydroxide (LDH) intercalated with CO32-, an anionic clay mineral, is applied for aqueous ammonia fuel cells as an electrolyte. PtRu/C and Pt/C are used for the anode and the cathode catalysts, respectively. Pelletized Mg-Al LDH powder is used as an electrolyte. The fuel cell works from room temperature to 80 degrees C with 50% of relative humidity of the air, and the power density increases with an increase in the cell temperature. This indicates that Mg-Al LDH allows the fuel cell working at rather high temperatures compared with cell using typical organic polymer anion exchange membranes.

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