4.6 Article

Bi2S3/BiOBr hybrid structure prepared via anion exchange for enhanced photocatalytic nitrogen fixation performance

Journal

MATERIALS LETTERS
Volume 253, Issue -, Pages 183-186

Publisher

ELSEVIER
DOI: 10.1016/j.matlet.2019.06.064

Keywords

Solar energy materials; Semiconductors; Bi2S3/BiOBr; Heterostructure; Photocatalytic; N-2 fixation

Funding

  1. National Natural Science Foundation of China [21877027]
  2. Program for Innovative Research Team in University of Henan Province [19 IRTSTHN023]
  3. Key Project of Science and Technology of Henan Province [17A150033]
  4. Science and technology key project of Xinxiang [CXGG17001]

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In this work, Bi2S3/BiOBr hybrid structure has been prepared via ion exchange method. The hybrid structure has enhanced light harvesting ability and improved transfer efficiency of photogenerated carriers thanks to the narrow bandgap of Bi2S3 and staggered band structure of Bi2S3/BiOBr hybrid structure. As a result, Bi2S3/BiOBr hybrid structure exhibits improved photocatalytic N-2 fixation performance compared with BiOBr and excellent stability after 4 cycles of photocatalytic nitrogen fixation under visible light irradiation. (C) 2019 Elsevier B.V. All rights reserved.

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