Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 41, Issue 1, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201900359
Keywords
autocatalysis; Click-reactions; copper-(I)-catalysis; polymer science; self-healing
Categories
Funding
- DFG [SPP 1568, SFB TRR 102]
- EU-IASS project
- Leistungszentrum System- und Biotechnologie (Uni-CBS1)
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The copper-catalyzed azide/alkyne cycloaddition reaction (CuAAC) has emerged as the most useful click chemistry. Polymer science has profited enormously from CuAAC by its simplicity, ease, scope, applicability and efficiency. Basic principles of the CuAAC are reviewed with a focus on homogeneous and heterogeneous catalysts, ligands, anchimeric assistance, and basic chemical principles. Recent developments of ligand design and acceleration are discussed.
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