Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 41, Issue 1, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201900460
Keywords
diarylbiindolinone; mechanochemistry; mechanochromic polymers; mechanophores; radicals
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Funding
- KAKENHI [17H01205]
- Japan Society for the Promotion of Science (JSPS)
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The synthesis and characterization of a series of diarylbiindolinone derivatives as substituent-tunable mechanochromophores that generate pink carbon-centered radicals in response to mechanical stimuli are reported. The changes in mechano-responsiveness, which result from the introduction of various substituents on the diarylbiindolinone skeleton, are systematically studied and mechanochromic polymers that contain such diarylbiindolinone units are developed.
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