Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 141, Issue 48, Pages 18926-18931Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b08415
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- Japan Science and Technology Agency (JST), Adaptable and Seamless Technology Transfer Program through Target-driven RD (A-STEP)
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A tantalum-catalyzed solvent-free approach for the construction of amide bonds with 1-(trimethylsilyl)imidazole is developed, and the mild reaction conditions are applicable to a wide variety of electrophilic amino acid homologues. This approach delivers a new class of peptides in high yields without any epimerization.
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