Journal
JOURNAL OF POWER SOURCES
Volume 440, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2019.227146
Keywords
Metal-organic frameworks; Nickel cobalt sulfide; N-doped carbon; Battery-supercapacitor hybrid cell; Energy storage
Funding
- National Key R&D Program of China [2017YFB0309400, 2017YFB0309100]
- National Natural Science Foundation of China [51303022]
- Fundamental Research Funds for the Central Universities [2232015D3-17]
- PhD Foundation for Innovation of Donghua University [17D310513]
- China Scholarship Council [201706630095]
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Based on a broad-sense modified one for two idea, the elaborately designed 3,4,9,10-perylene-tetracarboxylic-dianhydride (PTCDA)-based metal-organic frameworks (MOFs) are employed as the precursor for fabrication of both a battery-type (porous NiCo2S4) and a capacitive (N-doped carbon) electrode to form battery-supercapacitor hybrid cell (BSC). By inhering the topology of the precursor NiCo-PTCDA-MOFs, the derived NiCo2S4 is endowed with abundant effective pores. Meanwhile, combining the rigid planar structure of PTCDA and linked with N-containing 2,6-diaaino-anthraquinone (DAAQ) into polyquinoneimine (PQI) as a ligand, the Zn-PQI-MOFs-derived N-doped carbon shows high surface area. By coupling the porous NiCo2S4 with the N-doped carbon, the BSC demonstrates 234 C g(-1) at the current density of 1 A g(-1), remaining 56.4% of the initial specific capacity from 1 to 20 A g(-1). A high energy density of 51.98 W h kg(-1) at the power density of 0.8 kW kg(-1) surpasses those for the two symmetric cells made from similar electrodes. This work significantly extends the application of ligands with large conjugated structures in MOFs, which is essentially a new direction of MOFs-derived materials for energy storage.
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