4.5 Article

CeO2 nanoparticles embedded into one dimensional N doped carbon matrix as a high performance anode for lithium ion batteries

Journal

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
Volume 134, Issue -, Pages 187-192

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jpcs.2019.06.003

Keywords

CeO2; One dimensional; N doped; Carbon matrix; Lithium ion batteries

Funding

  1. National Natural Science Foundation of China [U1832147,11374043,11705015]
  2. Natural Science Foundation of Jiangsu Educational Department [15KJA430001]
  3. Foundation of Jiangsu science and Technology Department [BA2016041]
  4. Six -talent peak of Jiangsu Province [2012-XCL-036]
  5. Science and Technology Development Plan Project in Suzhou [SYG201738, SYZ201710]

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A facile method is designed to synthesize CeO2 nanoparticles embedded one dimensional N doped carbon matrix by the electrospinning and calcination process. The electrochemical tests reveal that the CeO2@NC composite delivers excellent electrochemical performance with good cycling stability and rate capability. CeO2@NC composite exhibits a high reversible capacity of 724.8 mAh g(-1) after 100 cycles at a current density of 100 mA g(-1), owing to that the one dimensional N doped carbon matrix can effectively improve the electron conductivity of composite and accelerate the ion transfer with short diffusion length. This work can be extended to construct one dimensional other metal oxides/carbon composite and applied in a new generation of anode materials.

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