Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 84, Issue 22, Pages 14369-14380Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b02465
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Funding
- Cornell University
- National Science Foundation [CHE-1751839]
- Alfred P. Sloan Foundation
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New catalytic strategies that leverage single-electron redox events have provided chemists with useful tools for solving synthetic problems. In this context, Ti offers opportunities that are complementary to late transition metals for reaction discovery. Following foundational work on epoxide reductive functionalization, recent methodological advances have significantly expanded the repertoire of Ti radical chemistry. This Synopsis summarizes recent developments in the burgeoning area of Ti radical catalysis with a focus on innovative catalytic strategies such as radical redox-relay and dual catalysis.
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