4.7 Article

A green and effective corrosion inhibitor of functionalized carbon dots

Journal

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
Volume 35, Issue 10, Pages 2243-2253

Publisher

JOURNAL MATER SCI TECHNOL
DOI: 10.1016/j.jmst.2019.05.045

Keywords

Q235 steel; Carbon dots; Adsorption; HCl solution

Funding

  1. Program of Qingjiang Excellent Young Talents, Jiangxi University of Science and Technology
  2. Natural Science Foundation of Jiangxi Province [20181BBE58001]
  3. Natural Science Foundation of Jiangxi Education Department [GJJ180431]

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In this work, a green and effective corrosion inhibitor of functionalized carbon dots (FCDs) was synthesized by the conjugation of imidazole and citric acid carbon dots (CA-CDs). The corrosion inhibition behavior of FCDs for Q235 steel in 1 M HCl solution was systematically investigated by electrochemical analysis, corrosion morphology and adsorption isotherm. The electrochemical results implied that the as-prepared FCDs inhibitor could effectively suppress the corrosion of Q235 steel in 1 M HCl solution. At the same time, the inhibition efficiency of steel in 1 M HCl solution was more than 90% when the inhibitor concentration exceeded 100 mg/L. This excellent property was attributed to the coverage of adsorption film on the steel surface, which conformed to the Langmuir adsorption model. In addition, the analysis of adsorption isotherm displayed that the adsorption mechanism was the physicochemical interaction at the steel/solution interface. (C) 2019 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

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